Montmorillonite KSF as a very efficient heterogeneous catalyst for the synthesis of 5-substituted 1H-tetrazoles
الموضوعات : Iranian Journal of Catalysis
Rahman Hosseinzadeh
1
(Department of Organic Chemistry, Factually of Chemistry, University of Mazandaran, Babolsar, Iran.)
Zahra Lasemi
2
(Department of Chemistry, Firoozkooh branch, Islamic Azad University, Firoozkooh, Iran.)
Farzaneh Maliji
3
(Department of Organic Chemistry, Factually of Chemistry, University of Mazandaran, Babolsar, Iran.)
الکلمات المفتاحية: Heterogeneous catalyst, Sodium azide, Nitriles, [3+2] Cycloaddition, Tetrazoles, Montmorillonite KSF,
ملخص المقالة :
Montmorillonite KSF has been used as an effective and non-toxic heterogeneous catalyst for one-pot synthesis of 5-substituted 1H-tetrazoles via [3+2] cycloaddition of sodium azide with a wide variety of nitriles. The reaction afforded high yields of the desired products in a short reaction time under mild reaction conditions. The catalyst can be recovered by simple filtration and reused for more consecutive trials without a significant decrease in activity. To avoid using toxic catalyst and catalyst recycling make this synthesis a truly green procedure.
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