A Nickel Sublayer: An Improvement in the Electrochemical Performance of Platinum-Based Electrocatalysts as Anodes in Glucose Alkaline Fuel Cells

الموضوعات : Iranian Journal of Catalysis

Behnam Moeini ¹ , Masoumeh Ghalkhani ² , Tahereh G. Avval ³ , Matthew R. Linford ⁴ , Rasol Abdullah Mirzaie ⁵

1 - Department of Chemistry and Biochemistry, Brigham Young University, C100 BNSN, Provo, Utah 84602, USA|Fuel Cell Research Laboratory, Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Tehran, Iran
2 - Fuel Cell Research Laboratory, Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Tehran, Iran
3 - Department of Chemistry and Biochemistry, Brigham Young University, C100 BNSN, Provo, Utah 84602, USA
4 - Department of Chemistry and Biochemistry, Brigham Young University, C100 BNSN, Provo, Utah 84602, USA
5 - Fuel Cell Research Laboratory, Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Tehran, Iran

تاريخ الإرسال : 02 الثلاثاء , ربيع الثاني, 1442 تاريخ التأكيد : 01 السبت , رجب, 1442 تاريخ الإصدار : 17 الإثنين , رجب, 1442

الکلمات المفتاحية: glucose, Platinum–Nickel electrocatalyst, Electrodeposition method, Alkaline fuel cell,

ملخص المقالة :

Platinum–nickel electrocatalysts supported on the modified carbon paper (MCP) were prepared by electrodeposition. Here, various procedures were applied for the electrodeposition of nickel and platinum particles, separately or simultaneously, on the surface of the MCP as an anode electrode for glucose alkaline fuel cells. The establishment of the best procedure for this fabrication is the main goal of this work. The obtained electrocatalysts were characterized by cyclic voltammetry, linear sweep voltammetry, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The results showed that the Pt/Ni electrocatalyst, electrodeposited from two separate solutions containing Ni and then Pt ions, has excellent electrocatalytic activity for the glucose oxidation reaction (GOR). On the other hand, the Pt/Ni/MCP electrode showed satisfactory repeatability when subjected to continuous cycling and less concentration polarization in the oxidation region of GOR (from -1 to 0.6 V vs. SCE). Also, the Pt/Ni/MCP electrode showed a significant increase in the exchange current density (0.95 mA cm-2) that accelerates the kinetics of the glucose oxidation reaction.These results indicate that modification of the catalyst layer structure in the present work is the most promising approach to achieve low-cost and efficient catalysts for use in glucose alkaline fuel cells.

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