Silica-bonded n-propyldiethylenetriamine sulfamic acid as a recyclable solid acid catalyst for the synthesis of coumarin and biscoumarin derivatives
الموضوعات : Iranian Journal of Catalysis
Khodabakhsh Niknam
1
(Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran.)
Seyed Ahmad Sajadi
2
(Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.)
Roghayeh Hosseini
3
(Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.)
Mojtaba Baghernejad
4
(Young Researchers and Elite Club, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.)
الکلمات المفتاحية: Catalyst, Aromatic aldehydes, Silica-bonded n-propyldiethylenetriamine sulfamic acid, Coumarins, Pechmann reaction, Biscoumarins, Solid acids,
ملخص المقالة :
Silica-bonded n-propyldiethylenetriamine sulfamic acid (SBPDSA) was found as an efficient solid acid for the synthesis of coumarins. Coumarin derivatives were obtained via the Pechmann condensation reaction of phenols and β-keto-esters at 80 oC under solvent-free conditions. Also, biscoumarins were obtained via the condensation of aldehydes and 4-hydroxycoumarin in water at reflux conditions. The heterogeneous solid acid showed much the same efficiency when used in consecutive reaction runs.
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