ابرخازن‌های پایه مکسن و چشم‌‏انداز آینده آن

الموضوعات :

طیبه محبی ¹ (دانشجوی دکتری گروه شیمی، دانشگاه کاشان، کاشان، ایران.)
مجید میرزایی ² (استادیار گروه پژوهشی مواد غیرفلزی، پژوهشگاه نیرو، تهران، ایران.)
مسعود همدانیان ³ (عضو هیات علمی گروه نانوشیمی(دانشیار)، دانشگاه کاشان، گروه شیمی،کاشان، ایران صندوق پستی: 51167-87317)

تاريخ الإرسال : 06 الثلاثاء , صفر, 1445 تاريخ التأكيد : 21 الأحد , صفر, 1446 تاريخ الإصدار : 26 الجمعة , صفر, 1446

الکلمات المفتاحية: چندسازه, مکسن, ابرخازن,

ملخص المقالة :

       مکسن‌‏‌‌ها (MXene) به‌­دلیل ساختار بی­‌همتا و گروه‏های عامل شیمیایی قابل‌تنظیم، یک سری ویژگی شگفت‏‌انگیز دارند. کاربرد مکسن‌‏ها در ذخیره‏‌سازی انرژی الکتروشیمیایی به­ویژه نشان‌­دادن پتانسیل بالا در کاربردهای ابرخازن توجه ویژه‏ای را به خود جلب کرده است. در مقایسه با سایر مواد، مکسن‌‏ها انعطاف مکانیکی بالا، چگالی انرژی بالا و کارایی الکتروشیمیایی خوبی دارند. بنابراین، به ویژه به­‌عنوان مواد الکترود برای ابرخازن­‌ها مناسب هستند. با این حال، مشابه سایر مواد دو بعدی، به­‌دلیل نیروهای قوی واندروالس، لایه‌های مکسن به‌ناچار انباشته می‌شوند که منجر به از دست­دادن شدید مکان‌های فعال الکتروشیمیایی می‌شوند. اگر بتوان تجمع لایه‌های مکسن را به‌طور مؤثری مهار کرد، کارایی الکتروشیمیایی آن‌ها افزایش می‌یابد. بهینه‏‌سازی ساختاری مکسن‌‏‏ها و دوپه‌­شدن آن­ها با مواد دیگر دو راه­برد موثر چشمگیر است. این مقاله، پیشرفت‌های اخیر در سنتز مکسن، ویژگی اساسی، و مواد چندسازه را با تمرکز بر آخرین کارایی الکتروشیمیایی الکترودها/دستگاه‌های مبتنی بر مکسن مرور می‌کند و چالش‌ها و فرصت‌های جدیدی را که مکسن در زمینه ذخیره‌سازی انرژی با آن مواجه است، ارائه می‌کند.

 

المصادر:

‎[1]‎‏ ‏Mirzaee M, Dehghanian C. Synthesis of flower-like NiCo2O4 via chronopotentiometric technique and its application as ‎electrode materials for high-performance supercapacitors. Materials Today Energy. 2018;10:68-8‎‏0.‏‎ doi: ‎org/10.1016/j.mtener.2018.08.011‎
‎[2] Mirzaee M, Dehghanian C. Pulsed electrodeposition of reduced graphene oxide on Ni-NiO foam electrode for ‎high-performance supercapacitor. International Journal of Hydrogen Energy. 2018;43(27):12233-5‎‏0.‏‎ doi: ‎org/10.1016/j.ijhydene.2018.04.173‎
‎[3] Mirzaee M, Dehghanian C, Sabet Bokati K. ERGO grown on Ni-Cu foam frameworks by constant potential ‎method as high performance electrodes for supercapacitors. Applied Surface Science. 2018;436:1050-6‎‏0.‏‎ doi: ‎org/10.1016/j.apsusc.2017.12.145‎
‎[4] Mirzaee M, Dehghanian C, Sabet Bokati K. One-step electrodeposition of reduced graphene oxide on three-‎dimensional porous nano nickel-copper foam electrode and its use in supercapacitor. Journal of ‎Electroanalytical Chemistry. 2018;813:152-62‎‏.‏‎ doi: org/10.‎‏1016/j.jelech‏em.2018.02.032‎
‎[5] Mirzaee M, Dehghanian C. Synthesis of Nickel-Nickel oxide foam by electrochemical method and its ‎application in supercapacitor. Advanced Processes‏ ‏in Materials Engineering. 2019;13(2):17-2‎‏5.‏‎ dor: ‎‏20.1001.1.24233226.1398.13.2.2.0‏
‎[6] Mirzaee M, Dehghanian C. Deposition of spinel cobalt nickel on nickel foam by a constant current ‎electrochemical method and its supercapacitor application. Journal of New Materials. 2019;10(35):39-4‎‏8.‏‎ dor: ‎‏20.1001.1.22285946.1398.9.35.4.6‏
‎[7] Gogotsi Y. What Nano Can Do for Energy Storage. ACS Nano. 2014;8(6):5369-7‎‏1.‏‎ doi: ‎org/10.1021/nn503164x
‎[8] Su Z, Yang C, Xie B, Lin Z, Zhang Z, Liu J, et al. Scalable fabrication of MnO2 nanostructure deposited on free-‎standing Ni nanocone arrays for ultrathin, flexible, high-performance micro-supercapacitor. Energy & ‎Environmental Science. 2014;7(8):2652-9‎‏.‏‎ doi: org/10‎‏.1039/C4EE01195C
‎[9] Er D, Li J, Naguib M, Gogotsi Y, Shenoy VB. Ti3C2 MXene as a High Capacity Electrode Material for Metal (Li, ‎Na, K, Ca) Ion Batteries. ACS Applied Materials & Interfaces. 2014;6(14):11173‎‏-9.‏‎ doi: ‎org/10.1021/am501144q
‎[10] Cai D, Huang H, Wang D, Liu B, Wang L, Liu Y, et al. High-Performance Supercapacitor Electrode Based on ‎the Unique ZnO@Co3O4 Core/Shell Heterostructures on Nickel Foam. ACS Applied Materials & Interfaces. ‎‏2014;6(18):15905-12.‏‎ doi: org/10.1021/am5035494‎
‎[11] Si C, Jin K-H, Zhou J, Sun Z, Liu F. Large-Gap Quantum Spin Hall State in MXenes: d-Band Topological ‎Order in a Triangular Lattice. Nano Letters. 2016;16(10):6584-9‎‏1.‏‎ doi: org/10.1021/acs.nanolett.6b03118‎
‎[12] Mirzaee M, Dehghanian C. Flower-like mesoporous nano NiCo2O4 -decorated ERGO/Ni-NiO foam as ‎electrode‏ ‏materials for supercapacitor. Materials Research Bulletin. 2019;109:10-2‎‏0.‏‎ doi: ‎org/10.1016/j.materresbull.2018.09.020‎
‎[13] Mirzaee M, Dehghanian C. Nanostructured Ni-Cu foam electrodeposited on a copper substrate applied as ‎supercapacitor electrode. Acta Metallurgica Slovaca. 2018;24(4):325-3‎‏6.‏‎ doi: 10.12776/ams.v24i4.1138‎
‎[14] Mirzaee M, Dehghanian C. Preparation of dendritic nanoporous Ni-NiO foam by electrochemical dealloying ‎for use in high-performance supercapacitors. Journal of Solid State Electrochemistry. 2018;22:3639-4‎‏5.‏‎ doi: ‎org/10.1007/s10008-018-4‎‏065-1‏
‎[15] Mirzaee M, Dehghanian C. Synthesis of nanoporous copper foam-applied current collector electrode for ‎supercapacitor. Journal of the Iranian Chemical Society. 2019;16:283-9‎‏2.‏‎ doi: org/10.1007/s13738-0‎‏18-‏‏1505-x
‎[16] Shao Y, El-Kady MF, Sun J, Li Y, Zhang Q, Zhu M, et al. Design and mechanisms of asymmetric ‎supercapacitors. Chemical Reviews. 2018;118(18):9233-80‎‏.‏‎ doi: org/‎‏10.1021/acs.c‏hemrev.8b00252‎
‎[17] Zhou Ruihua Charge storage by electrochemical reaction of water bilayers absorbed on MoS2 ‎monolayers. Scientific reports .2019; ‎‏9(1): 3980.‏‎ doi: org/10.1038/s41598-019-‎‏40672-w
‎[18] Mirzaee M, Dehghanian C, Sarbishei S. Facile synthesis of nano dendrite-structured Ni–NiO foam/ERGO by ‎constant current method for supercapacitor applications. Journal of Applied Electrochemistry. 2018;48:923-‎‏35.‏‎ doi: org/10.1007/s10800-018-1‎‏229-8‏
‎[19] Mirzaee M, Dehghanian C. Comparison between constant current electrochemical and pulse current approach ‎in‏ ‏reduction of graphene oxide on nickel-nickel oxide foam. Advanced Materials and New Coatings. ‎‏2019;7(28):2002-8.‏‎ doi: /AMNC.2019.7.28.4‎
‎[20] Borenstein A, Hanna O, Attias R, Luski S, Brousse T, Aurbach D. Carbon-based composite materials for ‎supercapacitor electrodes: A review. Journal of Materials Chemistry A. 2017;5(25):12653-7‎‏2.‏‎ doi: ‎org/10.1039/CTA00863E
‎[21] Nataf K, Bradley TH. An economic comparison of battery energy storage to conventional energy efficiency ‎technologies in Colorado manufacturing facilities. Applied Energy. 2016;164:133-9‎‏.‏‎ doi: ‎org/10.1016/j.apenergy.2015.11.102‎
‎[22] Wang‏ ‏F, Wu X, Yuan X, Liu Z, Zhang Y, Fu L, et al. Latest advances in supercapacitors: from new electrode ‎materials to novel device designs. Chemical Society Reviews. 2017;46(22):6816-5‎‏4.‏‎ doi: ‎org/10.1039/C7CS00205‎
‎[23] Divya K, Østergaard J. Battery energy storage technology for power‏ ‏systems—An overview. Electric power ‎systems research. 2009;79(4):511-20‎‏.‏‎ doi: org/10.1016/j.epsr.2008.09.017‎
‎[24] Zhou J, Zhang S, Zhou Y-N, Tang W, Yang J, Peng C, et al. Biomass-derived carbon materials for high-‎performance supercapacitors: Current status and perspective. Electrochemical Energy Reviews. 2021;4:219-‎‏48.‏‎ doi: org/10.1007/s41918-020-0‎‏0090-3‏
‎[25] Wang G, Zhang L, Zhang J. A review of electrode materials for electrochemical supercapacitors. Chemical ‎Society Reviews. 2012;41(2):797-828‎‏.‏‎ doi: org/10.1039/C1CS15060J
‎[26] Shan H, Qin J, Ding Y, Sari HMK, Song X, Liu W, et al. Controllable heterojunctions with a semicoherent ‎phase boundary boosting the potassium storage of CoSe2/FeSe2. Advanced Materials. 2021;33(37):2102471‎‏.‏‎ ‎doi: org/10.1002/adma.202102471‎
‎[27] Zhou Z, Seif A, Pourhashem S, Silvestrelli PL, Ambrosetti A, Mirzaee M, et al. Experimental and theoretical ‎studies toward superior anti-corrosive nanocomposite coatings of aminosilane wrapped layer-by-layer ‎graphene oxide@MXene/waterborne epoxy. ACS Applied Materials & Interfaces. 2022;14(45):51275-9‎‏0.‏‎ ‎doi: org/10.1021/acsami.2c14145‎
‎[28] Shi H, Zhang P, Liu Z, Park S, Lohe MR, Wu Y, et al. Ambient‐stable two‐dimensional titanium carbide ‎‎(MXene) enabled by iodine etching. Angewandte Chemie International Edition. 2021;60(16):8689-9‎‏3.‏‎ doi: ‎org/10.1002/anie.202015627‎
‎[29] Liu A, Liang X, Ren X, Guan W, Ma T. Recent progress in MXene-based materials for metal-sulfur and metal-‎air batteries: Potential high-performance electrodes. Electrochemical Energy Reviews. 2022:1-3‎‏3.‏‎ doi: ‎org/10.1007/s41918-021-0‎‏0110-w
‎[30] Gao Q, Sun W, Ilani-Kashkouli P, Tselev A, Kent PR, Kabengi N, et al. Tracking ion intercalation into layered ‎Ti3C2 MXene films across length scales. Energy & Environmental Science. 2020;13(8):2549-5‎‏8.‏‎ doi: ‎org/10.1039/D0EE01580F
‎[31] Zhu Y, Rajoua K, Le Vot S, Fontaine O, Simon P, Favier F. Modifications of MXene layers for supercapacitors. ‎Nano Energy. 2020;73:104734‎‏.‏‎ doi: org/10.1016/j.nanoen.2020.104734‎
‎[32] Tang J, Mathis T, Zhong X, Xiao X, Wang H, Anayee M, et al. Optimizing ion pathway in titanium carbide ‎MXene for practical high-rate supercapacitor. Advanced Energy Materials. 2021;11(4):2003025‎‏.‏‎ doi: ‎org/10.1002/aenm.202003025‎‏.‏
‎[33] Zhang Z, Yao Z, Zhang X, Jiang Z. 2D Carbide MXene under postetch low-temperature annealing for high–‎performance supercapacitor‏ ‏electrode. Electrochimica Acta. 2020;359:136960‎‏.‏‎ doi: ‎org/10.1016/j.electacta.2020.136960‎
‎[34] Cai C, Zhou W, Fu Y. Bioinspired MXene nacre with mechanical robustness for highly flexible all-solid-state ‎photothermo-supercapacitor. Chemical Engineering Journal. 2021;418:129275‎‏.‏‎ doi: org/10.1016/j.cej.2021.129275‎
‎[35] Lukatskaya MR‏, ‏Mashtalir O, Ren CE, Dall’Agnese Y, Rozier P, Taberna PL, et al. Cation intercalation and ‎high volumetric capacitance of two-dimensional titanium carbide. Science. 2013;341(6153):1502-5‎‏.‏‎ doi: ‎org/10.1016/j.cej.2021.129275‎
‎[36] Hu M, Li Z, Hu T, Zhu S, Zhang C, Wang X. High-capacitance mechanism for Ti3C2Tx MXene by in situ ‎electrochemical Raman spectroscopy investigation. ACS Nano. 2016;10(12):11344-5‎‏0.‏‎ doi: ‎org/10.1021/acsnano.6b06597‎
‎[37] Dall'Agnese Y, Lukatskaya MR, Cook KM, Taberna P-L, Gogotsi Y, Simon P. High capacitance of surface-‎modified 2D titanium carbide in‏ ‏acidic electrolyte. Electrochemistry Communications. 2014;48:118-2‎‏2.‏‎ doi: ‎org/10.1016/j.elecom.2014.09.002‎
‎[38] Li J, Yuan X, Lin C, Yang Y, Xu L, Du X, et al. Achieving High Pseudocapacitance of 2D Titanium Carbide ‎‎(MXene) by Cation Intercalation and Surface Modification. Advanced Energy Materials. ‎‏2017;7(15):1602725.‏‎ doi: org/10.1002/aenm.201602725‎
‎[39] Yang Q, Xu Z, Fang B, Huang T, Cai S, Chen H, et al. MXene/graphene hybrid fibers for high performance ‎flexible supercapacitors. Journal of Materials Chemistry A. 2017;5(42):22113-9‎‏.‏‎ doi: ‎org/10.1039/C7TA07999K
‎[40] Wang Y, Dou H, Wang J, Ding B, Xu Y‏, ‏Chang Z, et al. Three-dimensional porous MXene/layered double ‎hydroxide composite for high performance supercapacitors. Journal of Power Sources. 2016;327:221-8‎‏.‏‎ doi: ‎org/10.1016/j.jpowsour.2016.07.062‎
‎[41] Wen Y, Rufford TE, Chen X, Li N, Lyu M, Dai L, et al. Nitrogen-doped Ti3C2Tx MXene electrodes for high-‎performance supercapacitors. Nano Energy. 2017;38:368-7‎‏6.‏‎ doi: org/10.1016/j.nanoen.2017.06.009‎
‎[42] Sun L, Fu Q, Pan C. Hierarchical porous “skin/skeleton”-like MXene/biomass derived carbon fibers ‎heterostructure for self-supporting, flexible all solid-state supercapacitors. Journal of Hazardous Materials. ‎‏2021;410:124565.‏‎ doi: org/10.1016/j.jhazmat.2020.124565‎
‎[43] Liu Z, Wang L, Xu Y, Guo J, Zhang S, Lu Y. A Ti3C2TX@PEDOT composite for electrode materials of ‎supercapacitors. Journal of Electroanalytical Chemistry. 2021;881:114958‎‏.‏‎ doi: ‎org/10.1016/j.jelechem.2020.114958‎
‎[44] Yan J, Ma Y, Zhang C, Li X, Liu‏ ‏W, Yao X, et al. Polypyrrole–MXene coated textile-based flexible energy ‎storage device. RSC Advances. 2018;8(69):39742-8‎‏.‏‎ doi: 10.1039/C8RA08403C
‎[45] Zhang X, Shao B, Guo A, Gao Z, Qin Y, Zhang C, et al. Improved electrochemical performance of
CoOx-NiO/Ti3C2Tx MXene nanocomposites by atomic layer deposition towards high capacitance ‎supercapacitors. Journal of Alloys and Compounds. 2021;862:158546‎‏.‏‎ doi: ‎org/10.1016/j.jallcom.2020.158546‎
‎[46] Liang W, Zhitomirsky I. MXene–carbon nanotube composite electrodes for high active mass asymmetric ‎supercapacitors. Journal of Materials Chemistry A. 2021;9(16):10335-4‎‏4.‏‎ doi: org/10.1039/D0TA12485K ‎
‎[47] Ma L, Zhao‏ ‏T, Xu F, You T, Zhang X. A dual utilization strategy of lignosulfonate for MXene asymmetric ‎supercapacitor with high area energy density. Chemical Engineering Journal. 2021;405:126694‎‏.‏‎ doi: ‎org/10.1016/j.cej.2020.126694‎
‎[48] Mahmood M, Rasheed A, Ayman I, Rasheed T, Munir S, Ajmal S, et al‏.‏‎ Synthesis of ultrathin MnO2 ‎nanowire-intercalated 2D-MXenes for high-performance hybrid supercapacitors. Energy & Fuels. ‎‏2021;35(4):3469-78.‏‎ doi: org/10.1021/acs.energyfuels.0c03939‎
‎[49] Chen X, Liu Y, Zhou Q, Su F. Facile synthesis of MnO2/Ti3C2Tx/CC as positive electrode of all‐solid‐state ‎flexible asymmetric supercapacitor. ChemistrySelect. 2020;5(46):14768-7‎‏5.‏‎ doi: ‎org/10.1002/slct.202004181‎
‎[50] Yu L, Hu L‏, ‏Anasori B, Liu Y-T, Zhu Q, Zhang P, et al. MXene-bonded activated carbon as a flexible electrode for ‎high-performance supercapacitors. ACS Energy Letters. 2018;3(7):1597-603 doi: org/10.1021/acsenergylett.8b00718‎
‎[51] Miao J, Zhu Q, Li K, Zhang P, Zhao Q, Xu B. Self-propagating fabrication of‏ 3D porous MXene-‏rGO film ‎electrode for high-performance supercapacitors. Journal of Energy Chemistry. 2021;52:243-5‎‏0.‏‎ doi: ‎org/10.1016/j.jechem.2020.04.015‎
‎[52] Mirzaee M, Dehghanian C. Effect of different types of electrochemical methods on the super capacitor ‎properties of thin graphene oxide reduced by electrochemical method. Journal of Advanced Materials and ‎Technologies. 2020;9(2):35-42‎‏.‏‎ doi: org/10.30501/jamt.2020.185410.1031‎