4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) as a Bulky and Efficient Reagent for the Transformation of Symmetric and Asymmetric Benzoins to Corresponding Benziles
الموضوعات : Journal of the Iranian Chemical Research
Nader Noroozi Pesyan
1
(Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran)
Mahnaz Saraei
2
(Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran)
Bakhshali Massoumi
3
(Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran)
Maryam Sarbazi
4
(Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran)
الکلمات المفتاحية: 4-Chloro-3, 5-dioxaphosphacyclohepta[2, 1-, 3, 4-']dinaphthalene, Transformation reagent, Benzoin, Benzil,
ملخص المقالة :
4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) was found to be an efficient, bulky and selective reagent for the transformation of symmetric and asymmetric benzoins to the corresponding benziles at 0 °C to room temperature under nitrogen atmosphere in good yield.
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