Oxidative coupling of thiols to disulfides in solution radiation with Trimethylammonium Fluorochromate(VI), [(CH3)3NH[CrO3F], on Silica Gel

الموضوعات : Journal of the Iranian Chemical Research

Shahriar Ghammamy ¹ (Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran)

تاريخ الإرسال : 08 الثلاثاء , ربيع الأول, 1433 تاريخ التأكيد : 22 الأحد , جمادى الثانية, 1433 تاريخ الإصدار : 04 الخميس , ذو القعدة, 1433

الکلمات المفتاحية: Oxidation, Trimethylammonium fluorochromate(VI), Heterogeneous oxidants, Silica gel,

ملخص المقالة :

A mild and efficient method for the oxidative coupling of thiols by trimethylammonium fluorochromate(TriMFC) in solution is reported. Trimethylammonium fluorochromate is efficient and new reagent, whichprepares easily and oxidizes thiols to the corresponding disulfides quickly. The reactions perform cleanly andcontrolled to stop at the disulfide stage without over-oxidation side products.

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