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  • Insight into the Oxidant Agents Effect of Removal and Photo-decolorization of Vitamin B12 Solution in Drug Tablets using ZrO2

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عنوان URL للمقالة


رقم المقالة : 685757 زيارة : 183 الصفحة: 393 - 402

10.22034/jchr.2021.685757

نوع المخطوط: ابحاث

Insight into the Oxidant Agents Effect of Removal and Photo-decolorization of Vitamin B12 Solution in Drug Tablets using ZrO2

الموضوعات :

Shaymaa Ibrahim Saeed 1 , Ban Hasan Taresh 2 , Luma M. Ahmed 3 , Zainab Faisal Haboob 4 , Safa Alaa Hassan 5 , Athraa Abd Al-amir Jassim 6

1 - Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq, 56001
2 - Department of Clinical Laboratories, College of Applied Medical Sciences, University of Kerbala, Kerbala, Iraq, 56001
3 - Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq, 56001
4 - Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq, 56001
5 - Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq, 56001
6 - Department of Chemistry, College of Science, University of Kerbala, Kerbala, Iraq, 56001

تاريخ الإرسال : 29 الجمعة , ذو القعدة, 1442 تاريخ التأكيد : 19 الأحد , صفر, 1443 تاريخ الإصدار : 26 الأربعاء , ربيع الثاني, 1443

الکلمات المفتاحية: Zirconia, Vitamin B12, Oxidant reagents, Cyanocobalamin, Decolorization, Cobalamin, Removal, Photocatalytic,

ملخص المقالة :

The purpose of this manuscript was to remove and decolorize vitamin B12 from an aqueous solution of drug tablets using ZrO2 as an environmentally friendly method via advanced oxidation processes. Some oxidant agents such as Fe2+, H2O2, K2S2O8 and their mixture of were performed, and the best adsorption sequences have occurred with increased adsorption capacity: q(K2S2O8 + H2O2)>q(H2O2) >q (K2S2O8) >q (Fe2+ + H2O2) >q (Fe2+)>q (without) Endothermic and physical adsorption occurred of this vitamin on the ZrO2 surface with and without the addition of K2S2O8 +H2O2. On the other side, the photoreaction for this vitamin with and without the addition of K2S2O8 +H2O2 was found to be quick, endothermic, less random, and spontaneous. At 15 min, 33.223 % and 98. 684% were calculated as the maximum percentage of removal in the dark reaction and the maximum decolorization in the photocatalytic reaction respectively.

المصادر:


  1. Wiemhöfer H.D., Vohrer U.,1992. Spectroscopy and Thermodynamics of Electrons in Yttria‐Stabilized Zirconia. Ber Bunsenges Phys Chem. 96(11), 1646-1652.
    2.
  2. Mizuno N., 2009. Modern Heterogeneous Oxidation Catalysis: Design, Reactions, and Characterization, Wiley‐VCH Verlag GmbH & Co. KGaA, 22 April,84.
    3.
  3. Shahhiran A.F., Ramli R. M., 2021. Hayyiratul Fatimah Mohd Zaid, Modified Titania Impact on Photocatalytic Efficiency of Bmim [Cl]. Journal of Chemical Health Risks. 11(3), 283-290.
    4.
  4. Hussain Z.A., Fakhri F.H., Alesary H.F., Ahmed L.M., 2020. ZnO Based Material as Photocatalyst for Treating the Textile Anthraquinone Derivative Dye (Dispersive Blue 26 Dye): Removal and Photocatalytic Treatment. In IOP Conference Series: Journal of Physics: Conference Series, 1664, 012064, 1-15.
    5.
  5. Jaafar M.T., Ahmed L.M., 2020. Reduced the Toxicity of Acid Black (Nigrosine) Dye by Removal and Photocatalytic Activity of TiO2 and Studying the Effect of pH, Temperature, and the Oxidant Agents. AIP Conf. Proc. 2290, 030034-1– 030034-11.
    6.
  6. Hussein Z.A., Abbas S.K., Ahmed L.M., 2018. UV-A activated ZrO2 via photodecolorization of methyl green dye. In IOP Conference Series: Materials Science and Engineering. 454(1), 012132, IOP Publishing, pp. 1-11.
    7.
  7. Aghabeygi S., Sharifi Z., Molahasani N., 2017. Enhanced Photocatalytic Property of Nano-ZrO2-SnO2 NPs for Photodegradation of an Azo Dye. Digest Journal of Nanomaterials and Biostructures. 12(1), 81-89.
    8.
  8. Navio J., Hidalgo M., Colon G., Botta S., Litter M., 2001. Preparation and physicochemical properties of ZrO2 and Fe/ZrO2 prepared by a sol-gel technique. Langmuir. 17(1), 202–210.
    9.
  9. Rao M.B., Raju M., Sajjan M.S., Raju A.R.,2015. An Overview on Zirconia. TPDI. 6(2), 32 -36.
    10.
  10. Pokrovski K., Jung K.T., Bell A.T.,2001. Investigation of CO and CO2 adsorption on tetragonal and monoclinic zirconia. Langmuirm. 17(14),4297– 4303.
    11.
  11. Ma Z.Y., Yang C., Wei W., Li W.H., Su Y.H.,2005. Surface properties and CO adsorption on zirconia polymorphs. J Mol Catal A Chem. 227(1), 119–24.
    12.
  12. Kisi E.H., Howard C.J.,1998. Crystal Structures of Zirconia Phases and their Inter-Relation. Key Engineering Materials. 153-154, 1-36.
    13.
  13. Lughi V., Sergo V., 2010. Low temperature degradation -aging of zirconia: A critical review of the relevant aspects in dentistry. Dental Materials. 26, 807–820.
    14.
  14. Herbert V., 1988. Vitamin B-12: plant sources, requirements, and assay. The American Journal of Clinical Nutrition. 48(3), 852–858.
    15.
  15. Hayawi M.K., Kareem M.M., Ahmed L.M., 2020. Synthesis of Spinel Mn3O4 and Spinel Mn3O4/ZrO2 Nanocomposites and Using them in Photo-Catalytic Decolorization of Fe(II)-(4,5-Diazafluoren-9-One-11)Complex. Periódico Tchê Química. 17(34), 689-699.
    16.
  16. Ahmed L. M., Saaed S.I., and Marhoon A.A., 2018. Effect of Oxidation Agents on Photo-Decolorization of Vitamin B12 in the Presence of ZnO/UV-A System. Indones J Chem. 18(2), 272 – 278.
    17.
  17. Halbus A. F., Hussein F.H., 2012. Rapid Decolorization of cobalamin. International Journal of Photoenergy. pp.1-9.
    18.
  18. Guo W., Shen X., Wang L., Liang H. and Zhang L., 2011. TiO2‐assisted Photocatalytic Degradation of Vitamin B12 in Aqueous Solution: Influencing Factors Kinetics, and Reaction Investigations. Chinese Journal of Chemistry. 29(4), 661-668.
    19.
  19. Combs G.F., McClung J.P., 2017. The Vitamins, Fundamental Aspects in Nutrition and Health, 5th ed., Elsevier, Academic Press, Amsterdam.
    20.

20.Green R., Miller J.W., 2007. Vitamin B12- in Handbook of Vitamins, 4th ed., Eds. Zempleni J., Rucker R.B., McCormick D.B., and Suttie J.W, CRC Press, Taylor & Francis Group, USA,CH 13.

21.Yousaf H., Riaz S., 2018.  Biomolecular Evaluation of Cobalamin (Vitamin B12) in the Diabetic Population of Lahore and Sheikhupura. Ann Diabetes Metab Disord Contr. 2(1), 119.

  1. Ahmad I., Hussain W., and Fareedi A. A.,1992. Photolysis of cyanocobalamin in aqueous solution. Journal of Pharmaceutical and Biomedical Analysis. 10(1), 9–15.
    2.
  2. Kundu R., Biswas C., Ahmed J., Naime J., Ara M.H., 2020. A Study on the Adsorption of Cadmium(II) from Aqueous Solution onto Activated Carbon Originated from Bombax ceiba Fruit Shell. Journal of Chemical Health Risks.10(4), 243-252.
    3.
  3. Jawad T.M., AL-Lami M.R., Hasan A. S., Al-Hilfi J.A., Mohammad R.K., Ahmed L.M., 2021. Synergistic Effect of dark and photoreactions on the removal and photodecolorization of azo carmosine dye (E122) as food dye using Rutile- TiO2 suspension. Egypt J Chem. 64(9), 4857 – 4865.
    4.
  4. Karam F.F., Saeed N.H., Al-Yasari A.H., Ahmed L.M., Saleh H., 2020. Kinetic Study for Reduced the Toxicity of Textile Dyes (Reactive yellow 14 dye and Reactive green dye) Using UV-A light/ZnO System. Egypt J Chem. 63(8), 1-12.
    5.
  5. Alattar R.A., Saleh H.M., AL-Hilfi J.A., Ahmed L.M., 2020. Influence the addition of Fe2+ and H2O2 on removal and decolorization of textile dye (dispersive yellow 42 dye). Egypt J Chem. 63(9), 3191- 3201.
    6.
  6. Ahmed S., 2004. Photo electrochemical study of ferrioxalate actinometry at A glassy carbon electrode. Journal of Photochemistry and Photobiology A: Chemistry. 161, 151-154.
    7.
  7. Marhoon A.A., Saeed S.I. Ahmed L. M., 2019. Application of some effects on the Degradation of the aqueous solution of Fuchsine dye by photolysis. Journal of Global Pharma Technology. 11(9), 76-81.
    8.
  8. Abass S.K., Al-Hilfi J.A., Abbas S.K., Ahmed L.M., 2020. Preparation, Characterization and Study the Photodecolorization of Mixed-Ligand Binuclear Co (II) Complex of Schiff Base by ZnO. Indones J Chem. 20(2) 404 – 412.
    9.
  9. Alattar R.A., Hassan Z.M., Abass S.K., Ahmad L.M., 2020. Synthesis, Characterization and Study the Photodecolorization of Schiff Base Fe(III) Complex in ZnO/Uv-A Light System. AIP Conference Proceedings. 2290, 0300321-03003210.
    10.
  10. Salih E.F., Ahmed L.M., Mohammed A.F., 2020. Effect of silver doping on structural and photocatalytic circumstances of ZnO nanoparticles.Iraqi Journal of Nanotechnology, Synthesis and Application. 1, 13-20.
    11.
  11. Obaid A.J., Ahmed L.M., 2021. One-Step Hydrothermal Synthesis of α- MoO3 Nano-belts with Ultrasonic Assist for incorporating TiO2 as a NanoComposite. Egypt J Chem. 64(10), 5725 – 5734.
    12.
  12. Mahammed B.A., Ahmed L.M, 2017. Enhanced photocatalytic properties of pure and Cr-modified ZnS powders synthesized by precipitation method. J Geosci Environ Prot. 5(10), 101–111.
    13.
  13. Jawad T.M., Ahmed L.M., 2020. Direct Ultrasonic Synthesis of WO3/TiO2 Nanocomposites and Applyingthem in the Photodecolorization ofEosin Yellow Dye. Periódico Tchê Química. 17(34), 621-633.
    14.
  14. Pouretedal H.R., Hosseini M., 2010. Bleaching Kinetic and Mechanism Study of Congo Red Catalyzed by ZrO2 Nanoparticles Prepared by Using a Simple Precipitation Method, Acta Chim Slov. 57, 415-423.
    15.
  15. Ahmed L.M., Hussein F.H., Mahdi A.A., 2012. Photocatalytic dehydrogenation of aqueous methanol solution by naked and platinized TiO2 nanoparticles.  Asian Journal of Chemistry. 24(12), 5564-5568..
    16.
  16. Ahmed L.M., Ivanova I., Hussein F.H., Bahnemann D.W., 2014. Role of platinum deposited on TiO2 in photocatalytic methanol oxidation and dehydrogenation reactions. International Journal of Photoenergy. 1-9.
    17.
  17. Jaafar M., 2017. UV-A Activated ZnO Mediated Photocatalytic Decolorization of Nigrosine (Acid Black 2) Dye in Aqueous Solution. Journal of Geoscience and Environment Protection. 5, 138-147.
    18.
  18. Pérez-Sicairos S., Corrales-López K.A., Hernández-Calderón Ó.M., Salazar-Gastélum M.I, and Félix-Navarro R.M.,2016. Photochemical degradation of nitrobenzene by S2O8–2 ions and UV radiation. Rev Int Contam Ambie. 32 (2), 227–236.
    19.
  19. Mashkour M., Al-Kaim A., Ahmed L. and Hussein F., 2011. Zinc Oxide Assisted Photocatalytic Decolorization of Reactive Red 2 Dye. Int J Chem Sci. 9(3), 969-979.
    20.
  20. Jasim K.M., Ahmed L.M., 2019. TiO2 Nanoparticles Sensitized by Safranine O Dye using UV-A Light System. IOP Conference Series: Materials Science and Engineering. 571, 1-9.
    21.
  21. Saha P., Chowdhury S., 2001. Insight Into Adsorption Thermodynamics, Thermodynamics, Tadashi M. (Ed.), ISBN: 978-953-307-544-0, InTech.
    22.
  22. Zarrouk A., Hammouti B., Zarrok H., Al-Deyab S.S. and Messali M.,2011. Temperature Effect, Activation Energies and Thermodynamic Adsorption Studies of L-Cysteine Methyl Ester Hydrochloride As Copper Corrosion Inhibitor In Nitric Acid 2M. Int J Electrochem Sci. 6, 6261 – 6274.
    23.
  23. Ahmed L.M., 2018. Photo-Decolourization Kinetics of Acid Red 87 Dye in ZnO Suspension Under Different Types of UV-A Light. Asian J Chem. 30(9), 2134-2140.
    24.
  24. Zuafuani S.I.S., Ahmed L.M., 2015. Photocatalytic Decolourization of Direct Orange Dye Zinc Oxide Under Irradiation. Int J Chem Sci. 13(1), 187-196.
    25.
  25. Ahmed L.M., Jassim M.A., Mohammed M.Q., Hamza D.T.,2018. Advanced oxidation processes for carmoisine (E122) dye in UV-A/ZnO system: Influencing pH, temperature and oxidant agents on dye solution. Journal of Global Pharma Technology. 10(7), 248-254.
    26.
  26. Abbas S.K., Hassan Z.M., Ahmed L.M., 2019. Influencing the Artificial UV-A light on decolorization of Chlorazol black BH Dye via using bulk ZnO Suspensions. In Journal of Physics: Conference Series, IOP Publishing. 1294(5), 052050, 1-8.
    27.
  27. Ahmed L.M., Tawfeeq F.T., M. Al-Ameer H.A, Al-Hussein K.A., Athaab A.R., 2016. Photo-degradation of Reactive Yellow 14 dye (a textile dye) employing ZnO as photocatalyst, Journal of Geoscience and Environment Protection.  4(1), 34-44.
    28.
  28. Kzar K.O., Mohammed Z.F., Saeed S.I., Ahmed L.M., Kareem D.I., Hadyi H., and Kadhim A.J., 2019. Heterogeneous photo-decolourization of cobaltous phthalocyaninate dye (reactive green dye) catalyzed by ZnO. In AIP Conference Proceedings, 2144(1)020004, AIP Publishing LLC, 020004-01 -020004-10.
    29.
  29. Fakhri F.H., Ahmed L.M., 2019. Incorporation CdS with ZnS as nanocomposite and Using in Photo-Decolorization of Congo Red Dye. Indones J Chem. 19(4), 936 – 943.
    30.
  30. Mohammed B.A., Ahmed L.M., 218. Improvement the photo-catalytic properties of ZnS nanoparticle with loaded manganese and chromium by co-precipitation method. JGPT. 10(7), 129-138.
    31.
  31. Muruganandham M., Swaminatha M., 2006. TiO2-UV photocatalytic oxidation of Reactive Yellow 14: effect of operational parameters. J Hazrd Mater. 135, 78-86.
    32.
  32. Ahmed L. M., 2020. Bulk and Nanocatalysts Applications in Advanced Oxidation Processes, Oxidase, Licensee IntechOpen, UK.
    33.

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