A Facile Strategy for Synthesis of Well-defined Polypropylenegrafted-polystyrene /MMT Nanocomposite Using Reversible Addition: Fragmentation Chain Transfer Polymerization and Solution Intercalated Method
الموضوعات :Saber Ghasemi Karaj-Abad 1 , Parisa Shamsno 2 , Mojtaba Abbasian 3 , Mehdi Hosseinzadeh 4 , Solmaz Esmaeily Shoja 5
1 - Department of Chemistry, Payame Noor University, Tehran, Iran.
2 - Department of Chemistry, Payame Noor University, Tehran, Iran.
3 - Department of Chemical Engineering, University of Bonab, Bonab, Iran.
4 - Marand Faculty of Technical and Engineering, University of Tabriz, Tabriz, Iran.
5 - Faculty of Engineering, Islamic Azad University, Bonab Branch, Bonab, Iran.
الکلمات المفتاحية:
ملخص المقالة :
A simple and easy synthetic route for preparing PP-g-PSt/O-MMt nanocomposite was synthesized using a combination of ring-opening polymerization and reversible addition–fragmentation chain transfer polymerization techniques. Firstly, MAH (maleic anhydride) was reacted with PP (polypropylene) followed by the opening of an anhydride ring with ethanolamine to obtain a hydroxyl group including polypropylene (iPP-OH). Secondly, the produced PP-OH was treated with 4-cyano-4-[(phenylcarbothioyl) sulfanyl] pentanoic acid to synthesize of PP-RAFT macroinitiator. Then, the styrene monomer was grafted onto PP using RAFT approach to produce a well-defined (PP-g-PSt) copolymer. Finally, Polymer/clay nanocomposite was synthesized through a solution intercalation method. The successful synthesis of all materials was proved using FT-IR and 1H NMR spectroscopy. The structural morphology and thermal properties of the grafted copolymer /O-MMT nanocomposite were examined using SEM, TGA, and DSC. This approach employed via the RAFT method is an easy and alternative strategy for synthesizing new materials.
1.N.F. Himma, S. Anisah, N. Prasetya, I. G. Wenten, J. Polym. Eng., 36, 0112 (2015).
2. D. Li, Y. Shi, L. Yang, L. Xiao, D. K. Kehoe, Y. K. Gun’ko, J. J. Boland, J. J. Wang,Nature Food, 1, 746 (2020).
3. W. Hufenbach, R. B€ohm, M. Thieme, A. Winkler, E. M€ader, J. Rausch, M. Schade,Mater. Des, 32, 1468 (2011).
4. H. G. Ock, D. H. Kim, K. H.Ahn, S.J. Lee, J. M. Maia, Eur. Polym. J., 76, 216 (2016).
5. S.Wang, L.Wang, B.Wang, H. Su, W. Fan, X. Jinga, Polymer, 233, 124214 (2021).
6. Y. Wang, K. Gu, A. Soman, T.Gu, R. A. Register, Y.L. Loo, R. D. Priestley,Macromolecules., 53, 5740 (2020)
7. H. Mardani, H. R. Mamaqani, K. Khezri, M. S. Kalajahi, Applied Physics A., 126,251(2020).
8. Y. Wadaa, T. Kobayashi, H. Yamasaki, T. Sakata, N. Hasegawa, H. Mori, Y. Tsukahara,Polymer, 48, 1441 (2007).
9. E. V. Kolyakina, A. B. Alyeva, E. V. Sazonova, E. A. Zakharychev, D. F. Grishin, Polym.Sci B., 62, 328 (2020).
10. N. Naga, M. Sato, K. Mori, H. Nageh, T. Nakano, Polymers, 12, 2047 (2020).
11. X. Wang, L. Chen, L. Wang, Q. Fan, D. Pan, J. Li, F. Chi, Y. Xie, S. Yu, C. Xiao, F. Luo,J. Wang, X. Wang, C. Chen, W. Wu, W. Shi, S. Wang , X. Wang, Sci. China. Chem., 62, 933(2019).
12. N. Corrigan, K. Jung, G. Moad, C. J. Hawker, K. Matyjaszewski, C. Boyer, Prog. Polym.Sci., 111,101311 (2020).
13. P. R. Rodrigues, S. A. Gonçalves, R. P.Vieira, Eur. Polym. J., 147,110303 (2021).
14. R. Zeng, Y. Chen, L. Zhanga, J. Tan, Polym. Chem., 11, 4591 (2020).
15. L. Mrah, R. Meghabar, N Appl. Sci., 2, 659 (2020).
16. T.F.Menéndez, D.G.López, A.Argüelles, A. Fernández, J.Viña, Polym. Test., 90, 106729 (2020).
17. M. A. Aldosari, K.B.B. Alsaud, A. Othman, M. A. Hindawi, N. H. Faisal, R. Ahmed, F.M. Michael, M. R. Krishnan, E. Asharaeh, Polymers., 12, 1155 (2020).
18. H. Zhang, Eur Polym J. 49, 579 (2013)
19. M. Jaymand, M. Hatamzadeh, Y. Omidi, Prog. Polym. Sci., 47, 26 (2015).
20. A.A. Entezami, M. Abbasian, Iran. Polym. J., 15, 583 (2006).
21. M. Abbasian, M. Seyyedi, M. Jaymand, Polym. Bull., 77, 1107 (2020).
22. B. Massoumi, M. Abbasian, R. Mohammad‐Rezaei, A. Farnudiyan‐Habibi, M. Jaymand,Polym. Adv. Technol., 30, 1484 (2019).
23. R. Mohammad-Rezaei, B. Massoumi, M. Abbasian, M. Eskandani, M. Jaymand, J. Mater.Sci: Mater Electron, 30, 2821 (2019).
24. M. Abbasian, L. Razavi, M. Jaymand, S. Ghasemi Karaj-Abad, Scientia, Iranica, 26, 1447(2019).
25. M. Abbasian, M. Judi, F. Mahmoodzadeh, M. Jaymand, Polym. Adv. Technol., 29, 3097(2018).
26. R. Mohammad-Rezaei, B. Massoumi, M. Abbasian, M. Eskandani, M. Jaymand, J. Mater.Sci., 30, 2821 (2019).
27. S. Ghasemi Karaj-Abad, M. Abbasian, M. Jaymand, Carbohydr. Polym, 152, 297 (2016).
28. M. Barsbay, O.Güven, Rad.Phys.Chem, 169, 107816 (2020).
29. G. Moad, Aust. J. Chem., 59, 661 (2006).
30. D. HyoungKim, H.SungKim, Compos. Sci, Tech., 101, 110 (204)
31. M. Abbasian, F. Mahmoud Zade, J. Elastom. Plast, 49,173 (2017).
32. Le, T., PCT Int. Appl. WO 9801478 A1 980115” Chem. Abstr., (1998).
33. T. KO, P. Ning, Polym. Eng. Sci., 40, 1589 (2000).
34. H.Q. Xie, Z.S. Liu, J.S. Guo, Polymer, 35, 4914 (1998).
35. Q. Xiea, N, Liua, D. Lin, R. Qua, Qi. Zhou, F.Gea, Env Pollu., 263,114102 (2020).
36. L. Zhang, G. Fan, C. Guo, J. Dong, Y. Hu, M. Huang, Eur. Polym. J., 42, 1043 (2006).
