رقم المقالة : JNA-1707-1011 زيارة : 147 PDF XML

نوع المخطوط: ابحاث

Adsorption of phenol by super hydrophobic phenol-formaldehyde/silica hybrid aerogel

Mohamad Seraji ¹ ( ACECR, Production Technology Research Institute, Chemical Engineering Department, Ahwaz, Iran )
Sadra Soleimankhani ² ( ACECR, Production Technology Research Institute, Chemical Engineering Department, Ahwaz, Iran )
Hossein Abadani ³ ( Department of Chemical Engineering, Islamic Azad University, Abadan Branch, Iran )
Jamal Davarpanah ⁴ ( Chemistry Department, Production Technology Research Institute-ACECR, Ahvaz, Iran )

تاريخ الإرسال : 28 السبت , شوال, 1438 تاريخ التأكيد : 09 الجمعة , محرم, 1439

الکلمات المفتاحية: Removal, phenol, kinetic, Silica-based aerogel, Equilibrium isotherm,

ملخص المقالة :

Phenol-formaldehyde/silica hybrid gel with hydrophobic character, high porosity and small pore size mean was prepared via sol-gel polymerization under solvent saturated vapor atmosphere and was dried by ambient drying method. The silica sols were prepared based on Tetraethoxysilane (TEOS) and Methyltrimethoxysilane (MTES) as hydrophilic and hydrophobic precursors, respectively. Phenol-formaldehyde resin was used as polymeric phase to achieve suitable physical properties. The contact angle of this aerogel was about 147˚ and it is a result of formation of CH3 groups on the pore walls. The results of FESEM and nitrogen adsorption indicated that the structure of this aerogel is highly porous, uniform, and colloid like network. The Phenol-formaldehyde/silica hybrid aerogel was used for removal of phenol from aqueous solution. The study was carried out as functions of contact time, pH and initial phenol concentration. The experiments demonstrated that maximum phenol removal was obtained at neutral pH in unbuffered condition and it takes 40 min to attain equilibrium. Langmuir, Freundlich and Temkin isotherm models were applied to fit adsorption equilibrium data. The best-fitted data was obtained with the Langmuir model and the adsorbent capacity was 97.09 mg g−1. Kinetic studies indicated that the adsorption process was described better by pseudo-second-order model.

المصادر:

نص كامل:

Article

Adsorption of phenol by super hydrophobic phenol-formaldehyde/silica hybrid aerogel

Abstract

Keywords: Adsorption; Silica-based aerogel; Equilibrium isotherm; Kinetic; Phenol; Removal.

1. Introduction

Nowadays, phenolic compounds with a wide spectrum of water solubility, high toxicity, high volatility and reactivity are one of the most important water contaminations (Lorenc-Grabowska et al. 2016; Sunil and Jayant 2013). The presence of phenol derivatives with different concentrations in the agricultural, pharmaceutical, and petrochemical industry's wastewaters leads to a huge environmental and human health hazardous effects (Yoshida et al. 2016; Villegas et al. 2016). Therefore, phenol derivatives have been listed as priority pollutants by the environmental protection and health Agencies. A lot of researches have been carried out to find and modification of processes for achieving high capacity of phenol removal from wastewaters (Villegas et al. 2016). The physical, chemical and biological water waste treatments have been applied to removal of phenol derivatives. Adsorption technique is an effective conventional physical method for removal of organic compounds from water. This method has a proper effectivity for phenol removal from aqueous solutions in a wide range of phenol concentration (Roostaei and Tezel 2004). The mechanism of adsorption method is based on the type and magnitude of molecular interactions between adsorbent surface and dissolved adsorbate molecules in the liquid. In the last decades, a huge number of adsorbents and their capacity have been investigated for phenol included wastewater treatment (Singh and Srivastava 2002). Activated carbon is the most popular adsorbent for phenol adoption (Rincón-Silva et al. 2016). In despite of high capacity of activated carbon for phenol removal the non-selective chemical structure of these materials induced researchers to synthesis of novel selective nanostructures. Recently, new porous silica based nanostructures, silica aerogel and xerogels, with ultralow density, high porosity, high Surface area and controllable microstructure and chemical functionality have been interested for selective removal of phenol derivatives, which some of them are summarized in Table 1. According to these researches, the tailoring of silica structure to achievement of various hydrophobicity is related to amphiphilic properties of phenol derivatives. In addition, aerogels with high concentration of hydrophobic surface groups such as CH3 can control the diffusion of water and phenol derivatives into the aerogel pores and it leads to increasing of organic compounds entering to the porous structure in comparison of water molecules.

Table 1. Summary of properties and performance of silica based aerogel as phenol adsorbent

Adsorbent aerogel	Precursor	SBET (m2g−1)	Contact angle (˚)	Phenol derivative	Adsorption capacity (removal) Experimental condition	Ref
Hydrophobic silica aerogel	MTMS	512.4	-	phenol	21.1 mg g-1 contact time: 1 h	Perdigoto et al. 2012
Hydrophobic silica xerogel	MTMS	426.5	-	phenol	4.9 mg g-1 contact time: 1 h	Perdigoto et al. 2012
Hydrophobic silica aerogel	TEOS, TMCS	251-692	-	phenol	142 mg g-1 contact time: 25 h	Qin et al. 2013
Silica aerogel	MTMS, TMOS, β-CD	843- 938	35-107	Phenol, p-Cresol, 4-Chlorophenol, SDBS	117.8 mg g-1 contact time: 6 h	Matias et al. 2015
Water glass-based silica aerogel	TMCS, sodium silicate	579	143	phenol	38.46 mg g-1 contact time: 6 h	Firoozmandan et al. 2016
Water glass-based silica aerogel/activated carbon (AC) composite	TMCS, sodium silicate, AC	-	-	phenol	38.46 mg g-1 contact time: 6 h	Firoozmandan et al. 2016
Silica aerogel	sodium silicate	600-850	143	4-chlorophenol, 4-bromophenol	270.2703 mg g-1 contact time: 20 h	Abdoli et al. 2015
Silica Aerogel-Activated Carbon Nanocomposite	TMOS, MTMS	916	-	phenol	309.7 mg g-1 contact time: 23 h	Khanahmadzadeh et al. 2012
graphene aerogels–mesoporous silica	TEOS, Graphite	1000.80	-	Phenol, Catechol, Resorcinol, Hydroquinone	10.46 mg g-1 -	Wang et al. 2015

Recently, the preparation of polymer/silica hybrid aerogels has been attracted due to their unique properties and applications (Ramadan et al. 2010; Xu and Goedel 2002; Suchithra et al. 2002). In addition, Phenol-formaldehyde/silica aerogels with controllable microstructural properties has been synthesized successfully. The combination of polymeric phase through silica network leads to less shrinkage during the ambient drying and helps to prepare an ultralight, hyper porous nanostructure with a lower cost in comparison of supercritical drying (Seraji et al. 2015). Previously, we investigated the effect of process parameters on the microstructure and properties of phenol-formaldehyde (PF)/silica aerogels. The results showed that the increasing of hydrophobic characters on the pore walls cause to decreasing of surface area and the aerogel structure goes to polymeric hybrid system (Seraji et al. 2017).

In this paper, we investigate the removal capacity and isotherms of phenol removal by a new type of hybrid hyper porous nanostructure, phenol-formaldehyde (PF)/silica aerogels. To obtain the effective amphiphilicity and nanostructure, TEOS, phenol-formaldehyde resin, and MTES were used as co-precursors to formation of OH and CH3 groups. The preparation process was selected according to the best condition that is led to high porosity and surface area with high hydrophobicity properties. The equilibrium and kinetic studies were carried out for investigation of prepared aerogel's ability for phenol adsorption from aqueous solutions.

2. Experimental

2.1 Materials and aerogel preparation method

Phenol-formaldehyde resin (IP 502 Resitan Co. Iran) was used as polymeric thermoset phase. The amount of HMTA (hexamethylenetetramine) as crosslinking agent was 9 wt. % in the phenol-formaldehyde powder. Tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) (Merck) were used as inorganic precursor and co-precursor, respectively. 2-propanol was purchased from Merck and was used as solvent. Analytical grade of hydrochloric acid (Merck, Germany) was used as hydrolysis catalyst. Preparation of aqueous phenol solutions, analytical grade phenol (99%) was obtained from Merck. The preparation of hydrophobic hybrid aerogel was conducted by the demonstrated method in our previous work (Seraji et al. 2017). Firs one, three solutions of TEOS, MTES, and phenol-formaldehyde, were prepared. Hydrophilic silica based sol prepared with mixing of TEOS, 2-propanol, deionized water and HCl. The molar ratio of TEOS/H2O/HCl was 1:4:0.00018. Hydrophobic silica based sol was prepared with mixing of MTES, 2-propanol, deionized water and HCl. The molar ratio of MTES/H2O/HCl was 2.5:1.5:0.0001. Organic sol was prepared by dissolving phenol-formaldehyde resin in 2-propanol. Then, these three solutions were mixed together at optimum concentration for obtaining 3/1 mass ratio of TEOS and MTES. The solid content in the final mixture was kept at 10 wt. %. After it, the final solution, stirred and was cast into polypropylene mold and placed into an autoclave containing small amount of pure 2-propanol. The sol-gel polymerization was conducted for 20 hours at 120 ˚C. The synthesized gel was dried at ambient conditions and the final aerogel monolith was powder. To remove of impurities, the final powder was washed for two times and was dried.

2.2 Adsorbents characterization

Field emission scanning electron microscopy (MIRA3 TESCAN-RMRC) were used to characterization of microstructure and morphology of hybrid aerogel. EDX analysis was used to investigation of the silica fracture on the surface of aerogel. Pore size distribution and specific surface area were measured using the BET adsorption theory and the BJH desorption technique (Belsorp mini II, Japan). Water contact angle was measured with a Data physics OCA 15 plus (Germany) instrument.

2.3 Determination of organic compounds concentration

The adsorption of phenol from aqueous solutions was carried out at 25 ◦C. In general, 0.03 g of dry PF/silica aerogel pre-washed with distilled water (to eliminate impurities) was added to a 50 mL solution mixture of phenol (20 mg L-1) without pH adjustment and stirred for 40 min at 200 rpm. PF/silica aerogel were simply separated by passing the sample solution through an ordinary filter paper. The pH of the test solutions did not change during the removal experiments and remained nearly constant at about 7. The solution pH was measured by a Metrohm digital pH meter Model 632 (Herisau, Switzerland) using a combined glass electrode. The concentrations of phenol was determined by using a UV–Vis spectrophotometer model Jenway 620 (Stone, UK) using 10 mm path length quartz cell. The concentrations used in the calibration curves were in the range of 1-60 mg L-1 for phenol. The solutions were analyzed by measuring the absorbance at 270 nm.

The percentage of adsorbate removed from the aqueous solution was calculated using Eq. (1), where C0 (mg L−1) and Ce (mg L−1) are the initial and equilibrium adsorbate concentrations, respectively.

(1)

3. Results and Discussion

3.1 Characterization of the synthesized aerogel

As seen in the FESEM images, the solid phase of PF/silica aerogel is made of spherical particles with a varying size distribution. The distribution of particle size is due to the different chemistry and mechanism of sol-gel polymerization for organic and inorganic phases (Seraji et al. 2017). The particles with bigger dimensions attributed to the phenol/formaldehyde phase. As shown, the organic phase has been covered with amphiphilic porous silica phase (Fig. 1). In addition, the three-dimension network created with nanoparticles, leads to nano order open pores.

$C:\Users\Mehdi\Downloads\16276\16276\2 میکرون\sample 5-map.jpg$ $C:\Users\Mehdi\Downloads\16276\16276\200 نانومتر\sample 5-5.jpg$

Figure 1. FESEM micrograph of prepared aerogel

The EDX spectrum and element mapping of aerogels (Fig. 2) shows that the silica phase is dispersed in polymeric phase. The same distribution of Si and O in the mapping element shows the hydrophilic silica phase that are attributed Si-OH groups.

Figure 2. EDX spectra and element mapping of aerogels

According to the Fig. 3 the maximum pore size distribution occurs in a range less than 10 nm. The presence of micropores in the aerogel structures lead to formation of adsorption layer on the surface of pore's wall and it can be cause to more phenol removal by occurring of capillary condensation (Lorenc-Grabowska 2016). In despite of presence of micropores in PF/silica hybrid aerogel, one of the most important mechanisms for phenol removal by aerogels is filling of micropores with size smaller than 1.4 nm.

Figure 3. Pore size distribution obtained by nitrogen gas desorption for prepared aerogel

The Fig. 4 obviously shows that the PF/silica hybrid aerogel is strongly hydrophobic. The contact angle of this aerogel is about 147˚. This strong hydrophobicity is due to the fact that the OH groups that formed with TEOS condensation have been replaced end CH3 groups while (Perdigato et al. 2012; Qin et al. 2013). In the other hand, the presence of remained OH groups of silica phase account as hydrophobic characters.

Figure 4. Water droplet on the monolith surface and the image of contact angle test

3.2 Phenol removal

3.2.1 Effect of pH

The effect of pH on the adsorption of phenol was determined within the pH range of 2-10. The results are represented in Fig. 5. The maximum adsorption was determined at pH 7 that means the adsorption is higher at neutral pH. The optimum adsorption of phenol at pH 7.0 can be attributed to the phenol ionization capacity and point zero charge (pHpzc) of PF/Silicate. The pHpzc for PF/Silicate was obtained about 8.5. While the pH of the solution increases, the percentage of the ionized species increases; this is due to the fact that the pKa value of phenol is about 9.98 (Lorenc-Grabowska 2016). At pH 7.0 (pH 7.0 < pHpzc), there is no electrostatic repulsion between the unionized phenol species and the PF/Silicate surface and thus adsorption is higher. Therefore, all the adsorption experiments were carried out in unbuffered condition at neutral pH (pH ∼7) where the highest adsorptions were obtained.

Figure 5. The effect of pH on phenol removal by 0.03 g of PF/Silicate adsorbent at 25 ̊ C

3.2.2 Effect of contact time

The effect of contact time on the adsorption of phenol was investigated to determine the optimum time. Equilibrium adsorption curves of phenol, were obtained by following the same procedure with different contact time varying between 1 and 90 minutes. The adsorbate uptake (qe), expressed as adsorbate removal per unit mass of adsorbent (mg g−1), was calculated according to Eq. (2), where C0 is the initial adsorbate concentration (mg L−1), Ce the equilibrium concentration (mg L−1), V the batch volume (L) and m the adsorbent mass (g).

(2)

As shown in Fig 6, the amount of phenol adsorbed increases with contact time and attains equilibrium at about 40 min for same initial concentrations.

Figure 6. The effect of time on the removal of phenol by 0.03 g of PF/Silica adsorbent at pH 7 and 25 ̊ C

3.2.3 Effect of initial phenol concentration

The effect of initial phenol concentration on the removal of phenol was investigated by following the same procedure with different concentration varying between 5 and 60 mg L-1. The adsorption of phenol on PF/Silica decreases with increase in the phenol concentration, indicating that the adsorption is dependent upon the availability of binding site (Fig. 7). That means once adsorbate bind with the active site of adsorbent, the active site of PF/Silica is blocked. There is no further adsorption takes place on increase in concentration of phenol. Fig. 8 showed the decrease in adsorption with increase in the phenol concentration in the range 5-60 mg L-1.

$H:\Arshad 92\Jahad\2-Phenol\Graphic\Si-Phenol.jpg$

Figure 7. Schematic representation of adsorption of phenol on PF/Silica adsorbent. (Black: Novolac cyan: Silica red: Phenol

Figure 8. Effect of initial phenol concentration by 0.03 g of PF/Silica adsorbent at pH 7 and temperature: 25 ̊ C

3.2.4 Adsorption isotherms

Equilibrium parameters and adsorption properties of each isotherm model give useful information about the nature of interaction and indicate the interaction of adsorbent-adsorbate. For describing the relationship between the amount of phenol adsorbed on the PF/Silica and the phenol concentration; we need to use isotherms. The adsorption phenomena at the adsorbent surface are commonly described by Langmuir, Freundlich and Temkin isotherms (Liu et al. 2011; Kannan and Sundarm 2001; Langmuir 1916; Ghaedi et al. 2012; Temkin and Pyzhev 1940; Mittal et al. 2008). The Langmuir is the main monolayer adsorption model that its linear form is written as Eq. (3)

(3)

Where qe is the equilibrium adsorption amount of phenol (mg g−1), Ce is the equilibrium phenol concentration in the solution (μg mL−1), qm is the maximum adsorption amount of phenol per gram of adsorbent (mg g−1), and KL is the Langmuir adsorption equilibrium constant (L mg−1). The correlation coefficient was found to be 0.9967. The Freundlich isotherm is derived to model the multilayer adsorption and for the adsorption on heterogeneous surfaces. The Freundlich model is formulated as Eq. (4):

(4)

The equation may be linearized by taking the logarithm of both sides of Eq. (4) and linear form of Freundlich isotherm can be given as Eq. (5):

(5)

Where Ce is equilibrium concentration, qe designates the amount of phenol adsorbed at equilibrium in mg g−1, KF is the sorption capacity (mg g−1) and n is an empirical parameter. Adsorption data were also correlated with Freundlich model and a curve of ln qe vs. ln Ce was constructed. The Temkin isotherm describes the adsorption behavior on heterogeneous surfaces and is expressed by a linear Eq.

(6)

Where BT = RT/bT, T is the absolute temperature in 298K and R is the gas constant (8.314 J mol−1 K−1, KT is the equilibrium binding constant (L mg−1) and BT is related to the heat of adsorption. The values of the constants for isotherms were obtained from the slope and intercept of the curves of Langmuir, Freundlich, and Temkin isotherms have been shown in figs 9, 10, and 11, respectively.

Figure 9. The Langmuir isotherm plot for phenol adsorption on PF/Silica adsorbent. Amount of adsorbent: 0.03 g, pH 7, agitation speed: 200 rpm and temperature: 25 ̊ C

Figure 10. The Freundlich isotherm plot for phenol adsorption on PF/Silica adsorbent. Amount of adsorbent: 0.03 g, pH 7, agitation speed: 200 rpm and temperature: 25 ̊ C

Figure 11. The Temkin isotherm plot for phenol adsorption on PF/Silica adsorbent. Amount of adsorbent: 0.03, pH 7, agitation speed: 200 rpm and temperature: 25 ̊ C

The calculated constant values of the Langmuir, Freundlich, and Temkin isotherms along with their correlation coefficients are given in Table 2.

Table 2. Summary of properties and performance of silica based aerogel as phenol adsorbent

Langmuir isotherm			Freundlich isotherm			Temkin isotherm
qm (mg g-1)	KL (L mg-1)	R	KF (mg g-1)	N	r	BT (J mol-1)	KT (L g-1)	r
97.09	0.22	0.9967	22.51	0.233	0.9682	23.64	1.68	0.9889

It was observed that the experimental data are better fitted with the Langmuir isotherm (r = 0.9959) for the adsorption of phenol on the PF/Silica.

3.2.5 Kinetics of adsorption

The kinetic models were used to predict the variation of adsorbed phenol with time using PF/Silica. The rate constants of chemical adsorption were determined using the equations of the pseudo-first-order and pseudo-second-order models. Among procedures for the adsorption of a solute from aqueous solution, Pseudo-first-order model is one of the most widely used (Senturk et al. 2010; Abdelwahab 2008). The pseudo-first-order kinetic model of Lagergren can be given as Eq. (6):

(7)

Where qe and qt are the amounts of phenol adsorbed onto PF/Silica (mg g-1) at equilibrium and at time t, respectively, and K1 (1/min) is first-order rate constant for adsorption. The rate constant, K1, can be calculated from the plots of log (qe-qt) vs. t. Pseudo-second-order kinetics may be expressed as Eq. (7):

(8)

Where k2 is the rate constant of the second-order adsorption (g mg-1 min). The straight-line plots of t/qt against t have been tested to obtain rate parameters. The pseudo-first-order and pseudo-second-order kinetic models for phenol removal by PF/Silica were investigated using the above equations. The results indicate that the adsorption of phenol on PF/Silica is not fitted to a first-order model. However, the correlation coefficients for the second-order kinetic model were higher than 0.99 indicating the applicability of this kinetic model with the adsorption process of phenol on PF/Silica adsorbent.

Figure 12. Representative plot of the fit of linearized forms of pseudo-first-order equation to experimental adsorbed amounts of phenol on PF/Silica

Figure 13. Representative plot of the fit of linearized forms of pseudo- second-order equation to experimental adsorbed amounts of phenol on PF/Silica

Table 3. Kinetic parameters for the adsorption of phenol on PF/Silica adsorbent

C0 (mg L-1)	Pseudo-first-order equation			Pseudo- second-order equation
	K1 (10-3 min-1)	qe (mg g-1)	R2	K2 (10-2 min-1 g mg-1)	qe (mg g-1)	R2
20	0.052	9.57	0.962	0.03	28.25	0.9951

4. Conclusion

The super hydrophobic phenol-formaldehyde/silica hybrid aerogel prepared in this work indicate mesoporous structures, high surface area, and high level of hydrophobicity. Adsorption studies of phenol under different experimental conditions on PF/silica adsorbent have been undertaken. The percentage phenol removal is maximal at pH value of around 7, therefore, all the adsorption experiments were carried out at neutral pH in unbuffered condition. Adsorption kinetic by PF/silica adsorbent follows pseudo-second-order kinetic and interparticle diffusion model. The equilibrium data are analyzed using Langmuir, Freundlich and Temkin isotherm equations. The result shows that the experimental data are best correlated by Langmuir isotherm on PF/silica adsorbent.

Acknowledgments

We gratefully acknowledge the support of this work by Production Technology Research Institute-Academic Center for Education, Culture and Research and Abadan branch of Islamic Azad University.

References

1. E. Lorenc-Grabowska, Adsorption, 22(4-6) (2016) 599-607.

2. K. Sunil, K. Jayant, Adsorption, 1(2) (2013) 88-96.

3. S. Yoshida, S. Iwamura, I. Ogino, S.R. Mukai, Adsorption, 22(8) (2016) 1051-1058.

4. L.G.C. Villegas, N. Mashhadi, M. Chen, D. Mukherjee, K.E. Taylor, N. Biswas, Current Pollution Reports, 2 (3) (2016) 157-167.

5. N. Roostaei, F.H. Tezel, J. Environ. Manage., 70 (2) (2004) 157-164.

6. D.K. Singh, B. Srivastava, J. Sci. Ind. Res., 61 (2002) 208-212.

7. N.G. Rincón-Silva, J.C. Moreno-Piraján, L. Giraldo, Adsorption, 22 (1) (2016) 33-48.

8. M.L.N. Perdigoto, R.C. Martins, N. Rocha, M.J. Quina, L. Gando-Ferreira, R. Patrício, L. Durães, J. Colloid Interface Sci., 380 (1) (2012) 134-140.

9. G. Qin, Y. Yao, W. Wei, T. Zhang, Appl. Surf. Sci., 280 (2013) 806-811.

10. T. Matias, J. Marques, M.J. Quina, L. Gando-Ferreira, A.J. Valente, A. Portugal, L. Durães, Colloids Surf. A., 480 (2015) 260-269.

11. M. Firoozmandan, J. Moghaddas, N. Yasrebi, J. Sol-Gel Sci. Technol., 79 (1) (2016) 67-75.

12. S.M. Abdoli, D. Bastani, H. Bargozin, Sci. Iran., 22 (3) (2015) 992.

13. S. Khanahmadzadeh, N. Khorshidi, M. Rabbani, B. Khezri, J. Appl. Environ. Biol. Sci., 2 (7) (2012) 281-286.

14. X. Wang, M. Lu, H. Wang, Y. Pei, H. Rao, X. Du, Purif. Technol., 153 (2015) 7-13.

15. H. Ramadan, A. Ghanem, H. El-Rassy, Chem. Eng. J., 159 (1) (2010) 107-115.

16. H. Xu, W.A. Goedel, Langmuir, 18 (6) (2002) 2363-2367.

17. P.S. Suchithra, L. Vazhayal, A.P. Mohamed, S. Ananthakumar, Chem. Eng. J., 200 (2012) 589-600.

18. M.M. Seraji, A. Seifi, A.R. Bahramian, Mater. Des., 69 (2015) 190-196.

19. M.M. Seraji, G. Sameri, J. Davarpanah, A.R. Bahramian, J. Colloid Interface Sci., 493 (2017) 103-110.

20. E. Lorenc-Grabowska, Adsorption, 22 (4-6) (2016) 599-607.

21. R. Liu, B. Zhang, D. Mei, H. Zhang, J. Liu, Desalination, 268 (1) (2011) 111-116.

22. N. Kannan, M.M. Sundaram, Dyes pigm., 51 (1) (2001) 25-40.

23. I. Langmuir, J. Am. Chem. Soc., 38 (1916) 2221-2295.

24. M. Ghaedi, H. Tavallali, M. Sharifi, S.N. Kokhdan, A. Asghari, Spectrochim. Acta. Part A, 86 (2012) 107-114.

25. M.J. Temkin, V. Pyzhev, Acta Physico-Chimica Sinica, 12 (1940) 217-222.

26. A. Mittal, D. Kaur, J. Mittal, J. Colloid Interface Sci., 326 (1) (2008) 8-17.

27. H.B. Senturk, D. Ozdes, C. Duran, Desalination, 252 (1) (2010) 81-87.

28. O. Abdelwahab, Desalination, 222 (1-3) (2008) 357-367.

Adsorption of phenol by super hydrophobic phenol-formaldehyde/silica hybrid aerogel

سند

الروابط

المراكز ذات الصلة

دعامة

الصفحات الرسمية