3-Hydroxypropylammonium acetate (HPAA) ionic liquid: An effective acidic media in efficient conversion of anilines into aryl isocyanates
محورهای موضوعی : Iranian Journal of CatalysisDavood Azarifar 1 , Maryam Golbaghi 2 , Razieh Nejat-Yami 3
1 - Faculty of Chemistry, Bu-Ali Sina University, 65178, Hamedan, Iran
2 - Faculty of Chemistry, Bu-Ali Sina University, 65178, Hamedan, Iran
3 - Faculty of Chemistry, Tarbiat Modares University, Tehran, Iran
کلید واژه: aniline, Ionic Liquid, Isocyanates, 3-hydroxypropylammonium acetate, HPAA,
چکیده مقاله :
A simple and mild procedure for the conversion of anilines into aryl isocyanates is described using the 3-hydroxypropylammonium acetate (HPAA) ionic liquid as a novel and efficient media has been explored in the synthesis of aryl isocyanates from the reaction of substituted urea with sodium nitrite in a water immiscible solvent. This ionic liquid can be easily recovered and reused for many times without noticeable loss of activity.
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