Oxidation of benzylic alcohols with molecular oxygen catalyzed by Cu3/2[PMo12O40]/SiO2

محورهای موضوعی : Iranian Journal of Catalysis

Hamid Aliyan ¹ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Razieh Fazaeli ² (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Ahmad Reza Massah ³ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Hamid Javaherian Naghash ⁴ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)
Saeed Moradi ⁵ (Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran.)

تاریخ دریافت : 1389/11/25 تاریخ پذیرش : 1390/02/13 تاریخ انتشار : 1390/03/11

کلید واژه: green chemistry, aerobic alcohol oxidation, Polyoxometalates (POMs),

چکیده مقاله :

The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.

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