Synthesized of mixed-metal MOF comprising two ligands used as a heterogeneous catalyst for Knoevenagel condensation reacti
محورهای موضوعی : شیمی کاربردی
علیرضا عباسی
1
,
Saeideh Tavakoli
2
,
محمد یوسفی
3
,
Moayad Hosainisadr
4
1 - گروه شیمی معدنی، دانشکده شیمی، دانشگاه تهران، تهران، ایران
2 - Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran
3 - Department of Applied Chemistry, Faculty of Pharmaceutical Chemistry, Tehran Medical Sciences, Islamic Azad University, Tehran, Iran
4 - Department of chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran
کلید واژه: MOF, mixed metal-organic framework, catalyst, Knoevenagel condensation,
چکیده مقاله :
A new mixed metal–organic framework [Zn0.5 Cd0.5 (NH2BDC) (4-bpmbp)].2DMF (NH2BDC = 2-amino terephthalate; 4-bpmbp = N4, N4'-bis (pyridine-4-ylmethylene)-biphenyl-4,4'- diamine DMF = N,N-dimethylformamide) (Zn-Cd-MOF) has been synthesized under solvothermal conditions using Cd2+ and Zn2+ salt, NH2BDC as a rigid ligand and 4-bpmbp as pillar ligand. The material was characterized by Fourier transform infrared (FT-IR), powder Xray diffraction (PXRD), and inductively coupled plasma (ICP) techniques. Furthermore, the catalytic behavior of Zn-Cd-MOF toward the Knoevenagel condensation reaction was investigated and good catalytic capability was achieved
A new mixed metal–organic framework [Zn0.5 Cd0.5 (NH2BDC) (4-bpmbp)].2DMF (NH2BDC = 2-amino terephthalate; 4-bpmbp = N4, N4'-bis (pyridine-4-ylmethylene)-biphenyl-4,4'- diamine DMF = N,N-dimethylformamide) (Zn-Cd-MOF) has been synthesized under solvothermal conditions using Cd2+ and Zn2+ salt, NH2BDC as a rigid ligand and 4-bpmbp as pillar ligand. The material was characterized by Fourier transform infrared (FT-IR), powder Xray diffraction (PXRD), and inductively coupled plasma (ICP) techniques. Furthermore, the catalytic behavior of Zn-Cd-MOF toward the Knoevenagel condensation reaction was investigated and good catalytic capability was achieved
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