سنتز و شناسایی بایو-نانوکامپوزیت FeOOH-AC و کاربرد آن برای حذف رنگ آنیونی متیل اورنژ

محورهای موضوعی : فصلنامه علمی - پژوهشی مواد نوین

حکیمه شریفی فرد ¹ , راضیه حیاتی ²

1 - استادیار، گروه مهندسی شیمی، دانشگاه یاسوج، یاسوج، ایران
2 - استادیار، گروه مهندسی مواد، دانشگاه یاسوج، یاسوج، ایران

تاریخ دریافت : 1402/10/13 تاریخ پذیرش : 1403/02/08 تاریخ انتشار : 1402/08/01

کلید واژه: کربن فعال, جذب سطحی, پوست هسته زرد آلو, رنگ متیل اورنژ, جذب الکترواستاتیک,

چکیده مقاله :

چکیده مقدمه: امروزه به دلیل کاهش منابع آب شیرین و افزایش تقاضا در جهان، حذف انواع آلاینده ­ها از فاضلاب­های صنعتی، از جمله رنگ­ ها، به­ منظور استفاده مجدد از آن ها، توجه زیادی را به خود جلب کرده است. روش: در این پژوهش کربن فعال (AC)  با استفاده از فعال­سازی شیمیایی پوست هسته زردآلو سنتز شد، و سپس این جاذب به وسیله­ ی گروه ­های عاملی آهن (^[1]FeOOH-AC) اصلاح شد و به عنوان جاذب جهت حذف رنگ متیل اورنژ از محیط آبی استفاده شد. خواص این جاذبها با آنالیزهای BET، SEM، XRD و FT-IR شناسایی شد. یافته­ ها: تطبیق داده ­های تعادلی با مدل لانگمویر نشان داد که فرآیند جذب به صورت تک لایه است و حداکثر ظرفیت جذب جاذبهای AC و FeOOH-AC به­ترتیب برابر با mg/g6/174و mg/g 249 می­ باشد که این افزایش ظرفیت­ جذب بعد از اصلاح به ­دلیل ایجاد مکان های جذب مثبت آهن (Fe-O-H₂⁺) در سطح جاذب اصلاح شده است که با مکانیسم جذب الکترواستاتیک رنگ متیل اورنژ را جذب می­ کنند. همچنین مکانیسم ­های جذب فیزیکی به دلیل ساختار متخلخل جاذب و برهم­کنش π-π در جذب رنگ متیل اورنژ بر جاذب FeOOH-AC موثر هستند. تجزیه و تحلیل داده‌های سینتیکی با مدل‌های سینتیکی مختلف نشان داد که مدل سینتیک شبه مرتبه دوم با نتیجه تجربی هم خوانی دارد. با تعیین پارامترهای ترمودینامیکی گرمازا و خودبخودی بودن فرآیند جذب مشخص شد. نتیجه­ گیری: چرخه ­های متوالی جذب و واجذب بیانگر توانایی احیاء و استفاده مجدد جاذب سنتز شده می­ باشد که می­ تواند یک گزینه مناسب برای استفاده در ابعاد صنعتی باشد.  

چکیده انگلیسی:

Abstract Introduction: Nowadays, due to the reduction of fresh water resources and the increase in demand in the world, the removal of various pollutants, such as dyes, from industrial wastewaters to reuse them has received much attention. Methods: In this research, activated carbon (AC) was synthesized by the chemical activation of apricot kernel shell, and then, this adsorbent was modified by iron-containing functional groups (FeOOH-AC) and used as an adsorbent in the removal of methyl orange from the aqueous solution. The properties of these adsorbents were characterized using BET, SEM, XRD, and FT-IR analyses. Findings: The matching of the equilibrium data with the Langmuir model showed that the adsorption process is single-layer and the maximum adsorption capacity of AC and FeOOH–AC absorbents equal 174.6 mg/g and 249 mg/g, respectively. The increase in adsorption capacity after modification is due to the positive adsorption sites of iron (Fe-O-H₂⁺) on the surface of the modified adsorbent, which adsorb the methyl orange by electrostatic mechanism. Also, the physical adsorption due to the porous structure of the adsorbent and π-π interaction are the effective mechanisms in the adsorption of methyl orange on the FeOOH-AC adsorbent. The analysis of kinetic data with different models showed that the pseudo-second-order kinetic model is consistent with the experimental result. The spontaneity and exothermic nature of the adsorption process were determined by determining the thermodynamic parameters. Conclusion: The successive cycles of adsorption and desorption indicate the ability to regenerate and reuse the synthesized adsorbent, which can be a suitable option for use on the industrial scale.

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