بررسی تجمع غلظت فلز مس در برخی از گیاهان مرتعی (کاهوی وحشی، درمنه و گون) در اطراف معدن ذوب مس خاتون آباد شهر بابک
محورهای موضوعی : آب و محیط زیستفاطمه عین الهی پیر 1 , ساحل پاکزاد توچایی1 2
1 - عضو هیئت علمی دانشگاه زابل، پژوهشکده تالاب بین المللی هامون.
2 - عضو هیئت علمی دانشگاه زابل، پژوهشکده تالاب بین المللی هامون.
کلید واژه: فلز مس, گیاهان مرتعی, Lactuca serriola, Artemisia sieberi, Astragalus bisulcatus, معدن ذوب مس خاتون آباد شهربابک,
چکیده مقاله :
هدف از انجام مطالعه، تعیین غلظت فلز مس در کاهوی وحشیLactuca serriola، درمنه Artemisia sieberi و گون Astragalus bisulcatus در اطراف معدن ذوب مس خاتون آباد و مقایسه غلظت ها با استانداردهای موجود بود. نمونه برداری از گیاهان از فواصل 300، 600 و 1000 متری در جهت شمالی کارخانه در فروردین ماه 1389 انجام شد. نمونه های برداشت شده به آزمایشگاه منتقل گردیدند و پس از آماده سازی توسط Hot plate digester هضم شدند و غلظت فلز مس نمونه ها توسط دستگاه جذب اتمی Konic مدل NOVAA 300 اندازه گیری شد. غلظت فلز مس درکاهوی وحشی، درمنه و گـون نیز به ترتیب 33/5-59/17، 17/5 - 46/19 و 47/5 73/12 میکروگــرم بر گــرم اندازه گیری شد. بیشترین و کمترین غلظت فلز مس در تمامی نمونه ها به ترتیب در فاصله 1000 متری و 300 متری معدن به دست آمد. افزایش غلظت فلز مس با افزایش فاصله از کارخانه می تواند ناشی از جهت حرکت باد، وزن کم ذرات حاوی مس، ارتفاع دودکش کارخانه و عدم جذب ذرات ریز توسط میکروفیلتر دودکش معدن باشد. غلظت فلز مس از حد مجاز تعیین شده برای مصرف روزانه دام در مرتع بیشتر بود. بنابراین لازم است میزان غبار حاوی مس دودکش کارخانه کاهش یابد.
he aims of this study were survey of Cu concentration in some grassland plants including, Lactuca serriola, Artemisia sieberi and Astragalus bisulcatus around the Khatoon Abad melting and compared the Cu concentration in samples with available standards. Samples of plants were collected from 300, 600 and 1000m distances from melting area in April 2010. Samples were transferred to the laboratory, prepared and then digested with hot plate digester. Cu concentration was measured in samples with Konic Wonm 300 atomic absorption spectrophotometer.The Cu concentration in Lactuca serriola, Artemisia sieber and Astragalus bisulcatus was measured 5.33-17.59, 5.17-19.46 and 5.47-12.73 µg/gdw respectively. In all samples, highest concentration of Cu was measured in 1000m and lowest concentration of Cu was calculated in 300m distance from melting area. Similarly, the highest and lowest concentrations of Copper in all samples were obtained in 1000m and 300m distance from melting area respectively.High concentration of Cu with increasing the distance from melting area could be due to wind direction, weight of particles containing of Copper, height of chimney and not absorbed of some smallest particles with micro filter was embedded in the chimney. According to some available standards, Cu concentration was low in soil. Consequently, the particles containing of Copper must reduced from the chimney of melting Copper mine.
- Wcislo، E. Loven، Kucharski، D.R. and Szdzuj، J. (2008). Human health risk assessment case study: An Abandoned Metal Smelter site in Poland, Chemosphere. J of Geoch Explorو،96، pp:223-230.
- Censi، P. Spoto، S.E. Saino، F. Sprovieri، M. Mazzola، S. Nardone، G. Geronimo، S.I. Punturo، R. and Ottonello، D. (2006). Heavy metals in coastal water systems: Acase study from the northewestern Gulf of Tailand. Chemos, 64، pp:1167-1176.
- DeMoor, J.M. and Koropatnick, D.J. (2000). Metals and cellular signaling in mammalian cells. Cell, Molec Biol, 46، pp:367–381.
- Hagh Larsooliha، Sh, Amini، H. Hoodchi، M. and Najafi، Jh. (2006). Monitoring of air and soil pollution in Esfahan. J of Surv In Sci Agricul, 2، pp: 39-54.
- Lan، C.Y., Shu، W.S. and Wong، M.H. (1998). Reclamation of Pb/Zn mine tailings at Shaoguan, Guangdong Province, Peoples’ Republic of China: The role of river sediment and domestic refuse. Biores Tech, 65, No, 1، pp: 117–124.
- Ying، T. Yong-Ming، L. Chang-Yong، H. Jian، L. Zhen-Gao، L. and Christie، P. (2008). Tolerance of Grasses to Heavy metals and microbial functional diversity in soils contaminated with Copper Tailing, Pedos, 18, No, 3, pp:363-370.
- Xiu-Zhen, H. Dong-Mei, Z. De-Qian، C. Long, Z. Hai-Lin، H. and Hui, W. (2009). Heavy Metal Transfer from Soil to Vegetable in Southern Jiangsu Province, China, Pedos, 19، No، 3، pp: 305–311.
- Muchuweti, M. Birkett, J.W. Chinyanga, E., Zvauya, R. Scrimshaw, M.D. and Lister, J.N. (2006). Heavy metal content of vegetables irrigated with mixtures of wastewater and sewage sludge in Zimbabwe: implication for human health. Agricul Eco and Environ, 112, pp:41–48.
- Nordlind, K. (2002). Expression of heat shock proteins in heavy metal-provoked in amed Human skin. Immunophar, Immunotoxico, 24، pp:383-394.
- Zhang, Q. Zhang, L. Xiao, X. Su, Z. Zou, P. Hu, H. Huang, Y. He, Q. (2010). Heavy metals chromium and neodymium reduced phosphorylation level of heat shock protein 27 in human keratinocytes, Toxico in Vit, 24, pp: 1098–1104.
- Bekheirnia, M. Shamshirsaz, M. Kamkar, Gh. Erfanzadeh, N. Boozari, M. Tabatabaii, M. and Larijani, B. (2003). Copper status in joung thalassemic patients with major bone mineral density. J Of Tab Sha, 2, pp: 79-86.
- Ghorbanli, M. Misagh, F. and Asadollahi, B. (2007). Copper Chloride stress on chlorophyll content, accumulation of carbohydrate and some growth parameters in two cultivars of canola (Brassica napus). J Of Agro And Hortic, Vol, 76, pp: 61-73.
- Rion, B. and Alloway, J. (2004). Fudamental aspects of Zinc in soils and plants. Inter Zinc Asso, 12, pp:128-134.
- http://www.Daneshnameh.roshd.ir
- Hudson-Edwards, K.A. Macklin، M.G. Jamieson، H E et al. (2003). The impact of tailings dam spills and clean-up operations on sediment and water quality in river systems: the Agricul Guad, Amalc6 Ilar, Spain[J]. l18, pp: 221-239.
- Singh, A. Sharma، R.K. Agrawal, M. and Marshall, F.M. (2010). Health risk assessment of heavy metals via dietary intake of foodstuffs from the wastewater irrigated site of a dry tropical area of India, Food and Chemic Toxico, 24, pp:1098-1104.
- Jarmer, T. Vohland, M. Lilienthal, H. and Schnuge, E. (2008). Estimation of some chemical properties of an agricultural soil by spectro radiometric measurements. Pedos, 18, No, 2, pp: 163–170.
- Lehndorff, E. and Schwark, L. (2009). Biomonitoring airborne parent and alkylated three-ring PAHs in the Greater Cologne Conurbation I: Tem accum patt, 157, No، 4, pp:1323-1331.
- Prajapati, S.K. and Tripathi, B. D. (2008).Biomonitoring seasonal variation of urban air polycyclic aromatic hydrocarbons (PAHs) using Ficus benghalensis leaves. Environ Pollut, 151, No, 3, pp: 543-548.
- Steinbo, M. and Breen, J. (1999). Heavy metals in soil and vegetation at Shallee Mine, Silvermines, Co. Tipperary, Biol And Environ: 99، No، 1، pp: 37–42.
- Hudji، M. and Jalalian، (2004). Survey of Ni, Mg and Cd in soil and agricultural products around the Foolade Mobarakeh Melting area. J Of Sci and Techno in Agricul and Nat Res, 8، No، 3، pp: 55-66.
- Pérez, N., J. Pey, S. Castillo, M. Viana, A. Alastuey and X. Querol, 2008, Interpretation of the variability of levels of regional backgrounds aerosols in the western Mediterranean, Sci Of The Tot Environ 407(1):527-540.
- Chopin، F. I. B. and Alloway، B. J. (2007). Trace element partitioning and soil particle haracterization around mining and smelting areas at Tharsis, Ríotinto and Huelva, SW Spain, Sci of the Tot Environ, 373، pp: 488–500.
- Delijani، F. Kazemi، Gh. Jhervin Nia، M. and Khakshoor، M. (2009). Enrichment of heavy metals distribution in soils of South Pars Special economic Zone (Assaluyeh). Eigh Inter Cong Of Civil Engin, Shiraz University، Iran.
- Wang، LYan-bin، Y. Yi-Bin S. and Gang، W. (2006). Risk assessment of heavy metals in soils and vegetables around non-ferrous metals mining and smelting sites, Baiyin, China, J Of Environ Sci, 18، No، 6، pp:1124-1134.
- Soofi Siavash، R. (1995). Animal nutrition. Amidi Publication. pp: 141-142.
- Lassiter، J.W. Hardy، M. and Edwards، J. (1982). Animal nutrition, Rest Publ Comp, pp188 and 272.
- Washington، D. C. (1980). Mineral tolerance of domestic animals, Ntional Academy Of Sciences, Uni Sta Of Amer, pp: 164-166.
- Hong-Yan، R.H. Da-Fang، Z.A. Singh، N.P. JIAN-Jun, Dong-Sheng، Q.and Run-He، S. (2009). Estimation of As and Cu contamination in Agricultural soils around a mining area by Re.ectance spectroscopy: A case study. Ped, 19 No،6 ،pp:719-726.
- Moreno-Jim، J. Jes، Pe nalosa، E.M.R. Manzanoa، R. Carpena-Ruiza، O. Gamarrab R.and Estebana، E. (2009). Heavy metals distribution in soils surrounding an Abandone mine in NW Madrid (Spain) and their transference to wild .ora, J of Haz Mat, 162، pp:854–859.