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مقاله
1 - Rice husk ash (RHA): A Highly efficient solid acid catalyst for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers with CrO3Iranian Journal of Catalysis , شماره 4 , سال 5 , تابستان 2015A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of rice husk ash (RHA) is reported. All reactions were performed at room t چکیده کاملA mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of rice husk ash (RHA) is reported. All reactions were performed at room temperature in high to excellent yields. A new, efficient and green catalyst, heterogeneous reaction conditions, easy work-up of the products and high reaction rates are the main advantages of this method. پرونده مقاله -
مقاله
2 - Introduction of sulfonated rice husk ash as a highly efficient reusable catalyst for the protection of the hydroxyl groupIranian Journal of Catalysis , شماره 5 , سال 5 , پاییز 2015A mild, efficient and fast method for the trimethylsilyl (TMS), tetrahydropyranyl (THP) and methoxymethyl (MOM) protection of alcohols and phenols in the presence of sulfonated rice husk ash (RHA-SO3H) is reported. All reactions were performed at room temperature in hig چکیده کاملA mild, efficient and fast method for the trimethylsilyl (TMS), tetrahydropyranyl (THP) and methoxymethyl (MOM) protection of alcohols and phenols in the presence of sulfonated rice husk ash (RHA-SO3H) is reported. All reactions were performed at room temperature in high to excellent yields. All the products are separated and compared with authentic samples and/ or identified using different types of methods including FT-IR, 1H NMR and 13C NMR spectroscopy. Ease of the preparation and handling of the catalyst, heterogeneous reaction conditions, reusability of the catalyst, easy work-up procedure and short reaction times are the main advantages of this method, which make this procedure useful and attractive addition to the available methods. پرونده مقاله